7287-82-3

  • Product Name:1-(2-METHYLPHENYL)ETHANOL
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Product Details

Purity:99%

Chinese Factory Supply High Purity 7287-82-3 1-(2-METHYLPHENYL)ETHANOL

  • Molecular Formula:C9H12O
  • Molecular Weight:136.194
  • Refractive Index:1.5315 
  • Boiling Point:215.7°Cat760mmHg 
  • PKA:14.44±0.20(Predicted) 
  • Flash Point:104.2°C 
  • PSA:20.23000 
  • Density:0.995g/cm3 
  • LogP:2.04830 

7287-82-3 Relevant articles

Origin of the detrimental effect of lithium halides on an enantioselective nucleophilic alkylation of aldehydes

Pate, Franck,Duguet, Nicolas,Oulyadi, Hassan,Harrison-Marchand, Anne,Fressigne, Catherine,Valnot, Jean-Yves,Lasne, Marie-Claire,Maddaluno, Jacques

, p. 6982 - 6991 (2007)

(Chemical Equation Presented) The effect...

Ruthenium(II) supported by phosphine-functionalized N-heterocyclic carbene ligands as catalysts for the transfer hydrogenation of ketones

Humphries, Matthew E.,Pecak, Wiktoria H.,Hohenboken, Sallie A.,Alvarado, Samuel R.,Swenson, Dale C.,Domski, Gregory J.

, p. 138 - 143 (2013)

We have prepared and characterized two r...

Cinchona-Alkaloid-Derived NNP Ligand for Iridium-Catalyzed Asymmetric Hydrogenation of Ketones

Zhang, Lin,Zhang, Ling,Chen, Qian,Li, Linlin,Jiang, Jian,Sun, Hao,Zhao, Chong,Yang, Yuanyong,Li, Chun

supporting information, p. 415 - 419 (2022/01/12)

Most ligands applied for asymmetric hydr...

Nickel-Catalyzed Enantioselective Hydroboration of Vinylarenes

Tran, Hai N.,Stanley, Levi M.

supporting information, p. 395 - 399 (2021/12/27)

The enantioselective hydroboration of vi...

Effectiveness and Mechanism of the Ene(amido) Group in Activating Iron for the Catalytic Asymmetric Transfer Hydrogenation of Ketones

Xue, Qingquan,Wu, Rongliang,Wang, Di,Zhu, Meifang,Zuo, Weiwei

supporting information, p. 134 - 147 (2021/02/05)

I-interacting ligands of the diphosphino...

Manganese catalyzed asymmetric transfer hydrogenation of ketones

Zhang, Guang-Ya,Ruan, Sun-Hong,Li, Yan-Yun,Gao, Jing-Xing

supporting information, p. 1415 - 1418 (2020/11/20)

The asymmetric transfer hydrogenation (A...

7287-82-3 Process route

1-(2-bromophenyl)ethanol
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1-(2-bromophenyl)ethanol

methyl iodide
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methyl iodide

1-Phenylethanol
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1-Phenylethanol

1-O-tolyl-ethanol
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1-O-tolyl-ethanol

Conditions
Conditions Yield
1-(2-bromophenyl)ethanol; With diisopropylmagnesium; lithium 2-(dimethylamino)ethanolate; In diethyl ether; at -40 - 20 ℃; Inert atmosphere;
methyl iodide; With copper(I) cyanide di(lithium chloride); In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
 
2-Methylacetophenone
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1-(2-methylcyclohexyl)ethanone

1-O-tolyl-ethanol
7287-82-3

1-O-tolyl-ethanol

Conditions
Conditions Yield
With Rh*C4H8O*C18H15P; hydrogen; In tetrahydrofuran; at 30 ℃; for 5h; under 15001.5 Torr; Autoclave; Glovebox;
24 %Chromat.
59 %Chromat.
14 %Chromat.

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