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Purity:99%
(Chemical Equation Presented) The effect...
We have prepared and characterized two r...
Most ligands applied for asymmetric hydr...
The enantioselective hydroboration of vi...
I-interacting ligands of the diphosphino...
The asymmetric transfer hydrogenation (A...
1-(2-bromophenyl)ethanol
methyl iodide
1-Phenylethanol
1-O-tolyl-ethanol
Conditions | Yield |
---|---|
1-(2-bromophenyl)ethanol; With diisopropylmagnesium; lithium 2-(dimethylamino)ethanolate; In diethyl ether; at -40 - 20 ℃; Inert atmosphere;
methyl iodide; With copper(I) cyanide di(lithium chloride); In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
|
2-Methylacetophenone
2-Ethyltoluene
1-(2-methylcyclohexyl)ethanone
1-O-tolyl-ethanol
Conditions | Yield |
---|---|
With Rh*C4H8O*C18H15P; hydrogen; In tetrahydrofuran; at 30 ℃; for 5h; under 15001.5 Torr; Autoclave; Glovebox;
|
24 %Chromat. 59 %Chromat. 14 %Chromat. |
ortho-tolylmagnesium bromide
acetaldehyde
1-methyl-2-vinyl-benzene
methylmagnesium bromide
1-methyl-2-vinyl-benzene
2-Methylacetophenone
(S)-1-(2-Methylphenyl)ethanol
(R)-1-(2-methylphenyl)ethanol