What is the (R)-1-(2-CHLOROPHENYL)ETHANOL?

(R)-1-(2-CHLOROPHENYL)ETHANOL is , while it's Molecular Formula is C 8 H 9 ClO.

What is the CAS number for (R)-1-(2-CHLOROPHENYL)ETHANOL?

The CAS number of (R)-1-(2-CHLOROPHENYL)ETHANOL is 120466-66-2.

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120466-66-2

Product Name:(R)-1-(2-CHLOROPHENYL)ETHANOL

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Product Details

Purity:99%

High Quality 120466-66-2 Competitive Price, (R)-1-(2-CHLOROPHENYL)ETHANOL

Molecular Formula:C₈H₉ClO
Molecular Weight:156.612
Boiling Point:231.417 °C at 760 mmHg
PKA:14.05±0.20(Predicted)
Flash Point:93.758 °C
PSA：20.23000
Density:1.182 g/cm³
LogP:2.39330

120466-66-2 Relevant articles

Amino alcohol effects on the ruthenium(II)-catalysed asymmetric transfer hydrogenation of ketones in propan-2-ol

Takehara, Jun,Hashiguchi, Shohei,Fujii, Akio,Inoue, Shin-Ichi,Ikariya, Takao,Noyori, Ryoji

, p. 233 - 234 (1996)

A ruthenium(II) complex generated in sit...

Asymmetric reduction of ketones by the acetone powder of Geotrichum candidum

Nakamura, Kaoru,Kitano, Kazutada,Matsuda, Tomoko,Ohno, Atsuyoshi

, p. 1629 - 1632 (1996)

Reduction of ketones with a reductant, 2...

Pushing the limits: Cyclodextrin-based intensification of bioreductions

Rapp, Christian,Nidetzky, Bernd,Kratzer, Regina

, p. 57 - 64 (2021)

The asymmetric reduction of ketones is a...

B-Chlorodiiso-2-ethylapopinocampheylborane: An extremely efficient chiral reducing agent for the reduction of prochiral ketones of intermediate steric requirements

Brown,Veeraraghavan Ramachandran,Teodorovic,Swaminathan

, p. 6691 - 6694 (1991)

B-Chlorodiiso-2-ethylapopinocampheylbora...

Chiral Ru complex immobilized on mesoporous materials by ionic liquids as heterogeneous catalysts for hydrogenation of aromatic ketones

Lou, Lan-Lan,Dong, Yanling,Yu, Kai,Jiang, Shu,Song, Yang,Cao, Song,Liu, Shuangxi

, p. 20 - 27 (2010)

Four kinds of mesoporous material-suppor...

Asymmetric reduction of ketones with a germinated plant

Matsuo, Kiyoko,Kawabe, Sei-ichiro,Tokuda, Yosuke,Eguchi, Takashi,Yamanaka, Rio,Nakamura, Kaoru

, p. 157 - 159 (2008)

A germinated radish sprout was used as a...

Stereoselective Reduction of Prochiral Ketones, Using Aluminum Hydride Reagents Prepared from LiAlH4 and Chiral Diethanolamines

Vries, Erik F.J. de,Brussee, Johannes,Kruse, Chris G.,Gen, Arne van der

, p. 377 - 386 (1994)

The asymmetric reduction of prochiral ke...

Enantioselective oxidation of secondary alcohols using a chiral nitroxyl (N-oxoammonium salt) catalyst

Rychnovsky, Scott D.,McLernon, Terri L.,Rajapakse, Hemaka

, p. 1194 - 1195 (1996)

Synthesis of a fluorous ligand and its application for asymmetric addition of dimethylzinc to aldehydes

Sokeirik, Yasser S.,Mori, Hiroyuki,Omote, Masaaki,Sato, Kazuyuki,Tarai, Atsushi,Kumadaki, Itsumaro,Ando, Akira

, p. 1927 - 1929 (2007)

A new fluorous ligand was synthesized fr...

Enantioselective transfer hydrogenation of ketones with planar chiral?ruthenocene-based phosphinooxazoline ligands

Liu, Delong,Xie, Fang,Zhao, Xiaohu,Zhang, Wanbin

, p. 3561 - 3566 (2008)

1,2-Disubstituted planar chiral ruthenoc...

Asymmetric transfer hydrogenation of aromatic ketones catalyzed by SBA-15 supported Ir(I) complex under mild conditions

Shen, Yanbin,Chen, Qiu,Lou, Lan-Lan,Yu, Kai,Ding, Fei,Liu, Shuangxi

, p. 104 - 109 (2010)

A heterogeneous catalyst of Ir(I)-9-amin...

Oxidative kinetic resolution of secondary alcohols with salen-Mn(III)/NBS/NaClO system

Zhang, Yuecheng,Gao, Baosheng,Zhou, Qiao,Zhao, Jiquan

, p. 1797 - 1802 (2014)

The oxidative kinetic resolution of race...

Kinetic resolution of secondary alcohols. Enantioselective acylation mediated by a chiral (dimethylamino)pyridine derivative

Vedejs, Edwin,Chen, Xinhai

, p. 1809 - 1810 (1996)

Cinchona-Alkaloid-Derived NNP Ligand for Iridium-Catalyzed Asymmetric Hydrogenation of Ketones

Zhang, Lin,Zhang, Ling,Chen, Qian,Li, Linlin,Jiang, Jian,Sun, Hao,Zhao, Chong,Yang, Yuanyong,Li, Chun

supporting information, p. 415 - 419 (2022/01/12)

Most ligands applied for asymmetric hydr...

Enhancing cofactor regeneration of cyanobacteria for the light-powered synthesis of chiral alcohols

Fan, Jianhua,Zhang, Yinghui,Wu, Ping,Zhang, Xiaoyan,Bai, Yunpeng

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Cyanobacteria Synechocystis sp. PCC 6803...

Single-Point Mutant Inverts the Stereoselectivity of a Carbonyl Reductase toward β-Ketoesters with Enhanced Activity

Li, Aipeng,Wang, Ting,Tian, Qing,Yang, Xiaohong,Yin, Dongming,Qin, Yong,Zhang, Lianbing

, p. 6283 - 6294 (2021/03/16)

Enzyme stereoselectivity control is stil...

120466-66-2 Process route

: 2039-87-4,107830-52-4,26125-41-7
2-chlorostyrene

: 13524-04-4,120466-66-2,132437-66-2,131864-71-6
(S)-1-(2'-chlorophenyl)ethanol

: 19819-95-5
2-(2-chlorophenyl)-1-ethanol

: 13524-04-4,131864-71-6,132437-66-2,120466-66-2
(R)-1-(o-chlorophenyl)ethanol

Conditions

Conditions	Yield
2-chlorostyrene; With benzo[1,3,2]dioxaborole; rhodium complex 8; In toluene; at 20 ℃; for 2h; With sodium hydroxide; water; dihydrogen peroxide; In toluene; at 20 ℃; for 2h; Title compound not separated from byproducts;
2-chlorostyrene; With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(di[2-furyl]phosphanyl)cyclohexane; benzo[1,3,2]dioxaborole; In 1,2-dimethoxyethane; toluene; at -75 ℃; for 1h; With potassium hydroxide; dihydrogen peroxide; In 1,2-dimethoxyethane; Title compound not separated from byproducts;
With pinacol borane; 4 A molecular sieve; Rh(2,5-norbornadiene)2BF₄; In 1,2-dimethoxyethane; at 20 ℃; for 12h; Title compound not separated from byproducts.;

: 2039-87-4,107830-52-4,26125-41-7
2-chlorostyrene

: 13524-04-4,120466-66-2,132437-66-2,131864-71-6
(S)-1-(2'-chlorophenyl)ethanol

: 19819-95-5
2-(2-chlorophenyl)-1-ethanol

: 13524-04-4,131864-71-6,132437-66-2,120466-66-2
(R)-1-(o-chlorophenyl)ethanol

Conditions

Conditions	Yield
2-chlorostyrene; With benzo[1,3,2]dioxaborole; rhodium complex 8; In toluene; at 20 ℃; for 2h; With sodium hydroxide; water; dihydrogen peroxide; In toluene; at 20 ℃; for 2h; Title compound not separated from byproducts;
2-chlorostyrene; With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(di[2-furyl]phosphanyl)cyclohexane; benzo[1,3,2]dioxaborole; In 1,2-dimethoxyethane; toluene; at -75 ℃; for 1h; With potassium hydroxide; dihydrogen peroxide; In 1,2-dimethoxyethane; Title compound not separated from byproducts;
With pinacol borane; 4 A molecular sieve; Rh(2,5-norbornadiene)2BF₄; In 1,2-dimethoxyethane; at 20 ℃; for 12h; Title compound not separated from byproducts.;

120466-66-2 Upstream products

2142-68-9
1-(2-chlorophenyl)ethanone
2039-87-4
2-chlorostyrene
108-05-4
vinyl acetate
13524-04-4
2'-chloro-sec-phenethyl alcohol

120466-66-2 Downstream products

959999-91-8
2-propen-1-yl 1-{4-{[(1R)-1-(2-chlorophenyl)ethyl]oxy}-5-[(methyloxy)carbonyl]-2-thienyl}-1H-benzimidazole-5-carboxylate
929040-32-4
methyl 5-(5-bromo-1H-benzimidazol-1-yl)-3-{[(1R)-1-(2-chlorophenyl)ethyl]oxy}thiophene-2-carboxylate
1245927-55-2
C₂₁H₁₆BrClN₂O₃S
929040-33-5
5-(5-bromo-1H-benzimidazol-1-yl)-3-({(1R)-1-[2-chlorophenyl]ethyl}oxy)thiophene-2-carboxamide