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Purity:99%
|
Chemical Properties |
clear colorless liquid |
|
Uses |
Chiral building block. |
Five new aminoalcohols containing a 2,2'...
We report an OmpF loop deletion mutant, ...
Deracemization of racemic chiral compoun...
A nonenzymatic dynamic kinetic resolutio...
It is extremely difficult to anticipate ...
isopropyl butyrate
1-Phenyl-1-propanol
(R)-1-phenyl-1-propanol
(S)-1-phenyl-1-propanol
(R)-1-phenylpropyl butyrate
1-phenyl-propan-1-one
| Conditions | Yield |
|---|---|
|
With [(C4Ph4COHOCC4Ph4)(μ-H)][(CO)4Ru2]; Novozym(R) 435; 2,4-dimethylpentan-3-one; In toluene; at 70 ℃; for 40h; under 142.511 Torr;
|
84% |
dimethyl zinc(II)
diethylzinc
benzaldehyde
1-Phenylethanol
(S)-1-phenyl-1-propanol
| Conditions | Yield |
|---|---|
|
With catalyst: (-)-3-exo-(dimethylamino)isoborneol; In toluene; toluene-soln. of catalyst added Me2Zn at 30°C; after 15 min added Et2Zn; cooled to 0°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;
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2% 93% |
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With catalyst: (-)-3-exo-(dimethylamino)isoborneol; In toluene; toluene-soln. of catalyst added Et2Zn at 30°C; after 15 min added Me2Zn; cooled to 0°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;
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76% 8% |
Isopropenyl acetate
1-Phenyl-1-propanol
1-propenylbenzene
1-phenylpropyl acetate
propylcyclohexane
(S)-1-cyclohexylpropan-1-ol
(R)-1-phenyl-propyl hydroperoxide
(E)-2-Methyl-3-((S)-1-phenyl-propoxy)-propenal